Proceedings of the 2024 10th International Conference on Advances in Energy Resources and Environment Engineering (ICAESEE 2024)

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Study on the Regulation Mechanism of Octa-aminophenyl POSS on the Electrical Properties of Polypropylene

Authors
Xiaosi Lin1, *, Jianjun Lin1, Yi Li1, Jiawen Chen1
1Fujian Electric Power Technical College, State Grid Fujian Technical Training Centre, State Grid Fujian Electric Power Co., Ltd., Quanzhou, China
*Corresponding author. Email: xiaosi_lin_eee@163.com
Corresponding Author
Xiaosi Lin
Available Online 9 May 2025.
DOI
10.2991/978-94-6463-708-3_46How to use a DOI?
Keywords
Nanocomposite; Polypropylene; Breakdown strength; Space charge accumulation; Thermally stimulated depolarization current; Trap
Abstract

Elevated temperatures significantly contribute to the deterioration of electrical performance in polymeric insulation under HVDC conditions. To enhance the power transmission capacity, it’s crucial for new cable designs to incorporate insulation materials with superior high-temperature resistance, involving heightened breakdown strength, minimized space charge accumulation, and reduced conductivity. In this study, a small quantity (~1.0 phr) of Octa-aminophenyl POSS (OaPOSS), a type of supernano, is blended into polypropylene (PP) to create OaPOSS/PP nanocomposites with upgraded electrical properties. Through thermally stimulated depolarization current (TSDC) analysis, it was clear that the incorporation of OaPOSS enhanced both the trap level and the density of deep traps within the PP matrix. The functionality of OaPOSS is elucidated by examining both the interface between OaPOSS and pristine PP, and the role of the phenyl group in isolated OaPOSS particles. Ultimately, the introduction of OaPOSS presents a novel approach to adjusting the electrical characteristics of pure PP, paving the way for the design of non-cross-linked, eco-friendly thermoplastic insulation materials tailored for HVDC cable applications with exceptional electrical performance.

Copyright
© 2025 The Author(s)
Open Access
Open Access This chapter is licensed under the terms of the Creative Commons Attribution-NonCommercial 4.0 International License (http://creativecommons.org/licenses/by-nc/4.0/), which permits any noncommercial use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license and indicate if changes were made.

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Volume Title
Proceedings of the 2024 10th International Conference on Advances in Energy Resources and Environment Engineering (ICAESEE 2024)
Series
Atlantis Highlights in Engineering
Publication Date
9 May 2025
ISBN
978-94-6463-708-3
ISSN
2589-4943
DOI
10.2991/978-94-6463-708-3_46How to use a DOI?
Copyright
© 2025 The Author(s)
Open Access
Open Access This chapter is licensed under the terms of the Creative Commons Attribution-NonCommercial 4.0 International License (http://creativecommons.org/licenses/by-nc/4.0/), which permits any noncommercial use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license and indicate if changes were made.

Cite this article

risenwbib
TY  - CONF
AU  - Xiaosi Lin
AU  - Jianjun Lin
AU  - Yi Li
AU  - Jiawen Chen
PY  - 2025
DA  - 2025/05/09
TI  - Study on the Regulation Mechanism of Octa-aminophenyl POSS on the Electrical Properties of Polypropylene
BT  - Proceedings of the 2024 10th International Conference on Advances in Energy Resources and Environment Engineering (ICAESEE 2024)
PB  - Atlantis Press
SP  - 431
EP  - 438
SN  - 2589-4943
UR  - https://doi.org/10.2991/978-94-6463-708-3_46
DO  - 10.2991/978-94-6463-708-3_46
ID  - Lin2025
ER  -