Proceedings of the International Conference on Current Problems in Engineering and Applied Sciences (ICCPEAS 2025)

Electrical Properties of Pb and Sn Doped Crystals of the Pb0.75Sn0.25Te Solid Solution and Thermoelements Based on Them

Authors
N. M. Akhundova1, *, G. Z. Bagiyeva2, T. D. Aliyeva1, 2, G. D. Abdinova2
1Azerbaijan State University of Economics, Baku, Azerbaijan, AZ1001
2Institute of Physics of the Ministry of Science and Education of the Republic of Azerbaijan, Baku, Azerbaijan, AZ1141
*Corresponding author. Email: akhundova_naila@unec.edu.az
Corresponding Author
N. M. Akhundova
Available Online 14 May 2026.
DOI
10.2991/978-94-6239-668-5_21How to use a DOI?
Keywords
solid solution; crystal; vacancy; additive; thermoelectric figure of merit
Abstract

Single crystals of Pb0.75Sn0.25Te with additions of Pb and Sn up to 1.0 at.% were grown, thermoelement legs were created on their basis, and their electrical properties were studied in the range of ~ 77–300 K. It was shown that atoms of additional Pb or Sn at low contents, being located in cation vacancies of crystals, lead to a decrease in the hole concentration, a change in the conductivity type, an increase in the specific resistance ρ and contact resistance rk of the thermoelement legs, and at high contents, creating donor centers in the crystals, they reduce ρ and rk. The specific contact resistance of the legs, as well as their temperature dependences, are also determined by the diffusion of the connecting alloy components into the near-contact region of the crystals. The thermoelectric figure of merit of the studied crystals with a 1.0 at.% Pb additive and the legs of thermoelements based on them reach values of 1.7 × 10–3 K−1 and 1.16 × 10−3K−1, respectively, at ~ 300 K.

Copyright
© 2026 The Author(s)
Open Access
Open Access This chapter is licensed under the terms of the Creative Commons Attribution-NonCommercial 4.0 International License (http://creativecommons.org/licenses/by-nc/4.0/), which permits any noncommercial use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license and indicate if changes were made.

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Volume Title
Proceedings of the International Conference on Current Problems in Engineering and Applied Sciences (ICCPEAS 2025)
Series
Advances in Engineering Research
Publication Date
14 May 2026
ISBN
978-94-6239-668-5
ISSN
2352-5401
DOI
10.2991/978-94-6239-668-5_21How to use a DOI?
Copyright
© 2026 The Author(s)
Open Access
Open Access This chapter is licensed under the terms of the Creative Commons Attribution-NonCommercial 4.0 International License (http://creativecommons.org/licenses/by-nc/4.0/), which permits any noncommercial use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license and indicate if changes were made.

Cite this article

TY  - CONF
AU  - N. M. Akhundova
AU  - G. Z. Bagiyeva
AU  - T. D. Aliyeva
AU  - G. D. Abdinova
PY  - 2026
DA  - 2026/05/14
TI  - Electrical Properties of Pb and Sn Doped Crystals of the Pb₀.₇₅Sn₀.₂₅Te Solid Solution and Thermoelements Based on Them
BT  - Proceedings of the International Conference on Current Problems in Engineering and Applied Sciences (ICCPEAS 2025)
PB  - Atlantis Press
SP  - 198
EP  - 205
SN  - 2352-5401
UR  - https://doi.org/10.2991/978-94-6239-668-5_21
DO  - 10.2991/978-94-6239-668-5_21
ID  - Akhundova2026
ER  -