Proceedings of the 1st International Symposium on African Sustainable Energy Solutions (AfrSusEnS 2024)

The Mechanism of Non-Catalytic CO2 Reduction in Non-Thermal Plasma Environment – In Situ FTIR Studies

Authors
Julia Moszczyńska1, Xinying Liu2, Yali Yao2, Marek Wiśniewski1, *
1Faculty of Chemistry, Nicolaus Copernicus University in Toruń, Gagarina 7, 87-100, Torun, Poland
2Institute for Catalysis and Energy Solutions, University of South Africa, c/o Christiaan de Wet & Pioneer, Florida, 1709, Roodepoort, Gauteng, South Africa
*Corresponding author. Email: marekw@umk.pl
Corresponding Author
Marek Wiśniewski
Available Online 22 July 2025.
DOI
10.2991/978-94-6463-797-7_6How to use a DOI?
Keywords
Carbon dioxide splitting; non-thermal plasma; mechanism
Abstract

Carbon dioxide conversion is considered a promising solution to the problem of global warming and the need for renewable energy storage. Although it is challenging to develop a process that combines the complete conversion of CO2 to CO in the absence of O2, this paper describes such a solution. In this study, the CO2 splitting was investigated and monitored in situ using a plasma generated in a DBD reactor without the participation of a catalyst. The results of excited-phase FTIR spectra indicate that gaseous H2, in contrast to Ar, acting as a scavenger of excited CO2 species significantly improves the process efficiency and minimizes the formation of oxygen.

Copyright
© 2025 The Author(s)
Open Access
Open Access This chapter is licensed under the terms of the Creative Commons Attribution-NonCommercial 4.0 International License (http://creativecommons.org/licenses/by-nc/4.0/), which permits any noncommercial use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license and indicate if changes were made.

Download article (PDF)

Volume Title
Proceedings of the 1st International Symposium on African Sustainable Energy Solutions (AfrSusEnS 2024)
Series
Advances in Engineering Research
Publication Date
22 July 2025
ISBN
978-94-6463-797-7
ISSN
2352-5401
DOI
10.2991/978-94-6463-797-7_6How to use a DOI?
Copyright
© 2025 The Author(s)
Open Access
Open Access This chapter is licensed under the terms of the Creative Commons Attribution-NonCommercial 4.0 International License (http://creativecommons.org/licenses/by-nc/4.0/), which permits any noncommercial use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license and indicate if changes were made.

Cite this article

TY  - CONF
AU  - Julia Moszczyńska
AU  - Xinying Liu
AU  - Yali Yao
AU  - Marek Wiśniewski
PY  - 2025
DA  - 2025/07/22
TI  - The Mechanism of Non-Catalytic CO₂ Reduction in Non-Thermal Plasma Environment – In Situ FTIR Studies
BT  - Proceedings of the 1st International Symposium on African Sustainable Energy Solutions (AfrSusEnS 2024)
PB  - Atlantis Press
SP  - 36
EP  - 43
SN  - 2352-5401
UR  - https://doi.org/10.2991/978-94-6463-797-7_6
DO  - 10.2991/978-94-6463-797-7_6
ID  - Moszczyńska2025
ER  -